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Nature and Growth of Interaction Layers Formed during the Reaction between Solid Ni and Liquid Al

Qiangang XU , Haifeng ZHANG , Bingzhe DING , Zhuangqi HU

材料科学技术(英)

The nature and growth of the interaction layers between solid Nb and liquid Al has been studied by carrying out the tests on Nb(s)-Al(l) and Nb(s)-Al(l)-Ni(s) reaction couples isothermally reacted between 700°C and 900°C for different time intervals. It has been found that the interaction layer between Nb and Al contains two parts: a thin continuous layer of NbAl3 adjacent to the Nb surface and a two-phase zone constituted of NbAl3 particles dispersed in an Al matrix. Although the nature and growth of interaction layers follows the four-stage mechanism, a typical cruciform pattern does not occur in Nb(s)-Al(l) reaction couples. However, a cruciform pattern was observed in Nb(s)-Al(l)-Ni(s) reaction couples. The movement of NbAl3 particles is important to the production of cruciform pattern in the reaction couples.

关键词: Wetting , null , null

Effect of Grain Boundary on the Wettability and Interfacial Morphology in the Molten Bi/Cu System

Qiangang XU , Haifeng ZHANG , Bingzhe DING , Zhuangqi HU

材料科学技术(英)

The wetting behavior of molten Bi on polycrystalline Cu substrate and single crystal Cu substrate was studied by the sessile drop method in the temperature range from 673 to 873K. At low temperature the wetting behaviors of molten Bi on both types of Cu substrate were similar. However, at high temperature, the equilibrium contact angle of polycrystalline Cu substrate was lower than that of single crystal Cu substrate, because the preferred dissolution of grain boundaries leads to a smaller liquid/solid interfacial energy for polycrystalline Cu substrate. The formation mechanism of arrow-shaped Cu grains at the Bi/single crystal Cu interface is also discussed.

关键词: Wettability , null , null , null

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